CO oxidation and CO-PROX reactions over Au catalysts supported on different metal oxides: a comparative study
نویسندگان
چکیده
منابع مشابه
Selective CO Oxidation over Au Supported On Mixed Oxides: Effect of Preparation on Activity and Selectivity
Au/CeLaOx mixed oxide catalysts containing 0.5 to 1.0 wt% Au were prepared via coprecipitation with HAuCl4, the appropriate nitrate precursors, and either urea or Na2CO3 as the precipitant. BET surface area measurements for the Au/CeLaOx catalysts varied in the range of 16-107 m/g depending on the precipitant, aging time, and calcination conditions. The catalysts were tested for the selective o...
متن کاملThe Effects of Water on CO Oxidation over TiO2 Supported Au Catalysts
Polarization modulation infrared reflection absorption spectroscopy (PM-IRAS) was used to investigate the effects of water on CO oxidation catalyzed by TiO2 supported Au. The introduction of water into the reactant mixture caused two effects: (1) a decrease in the CO coverage; and (2) the appearance of a carbonate species. Since both effects inhibit CO oxidation, the promotional effects of wate...
متن کاملCO oxidation on TiO2 supported gold catalysts
The aim within this project was to optimise the CO oxidation over TiO2 supported gold catalysts, focusing on two different preparation methods; deposition precipitation (DP) and photodeposition (PD), using different types of TiO2 and varying the theoretical gold loading. The catalyst were characterised with TEM (size) and ICP-AES (loading). For DP catalysts, the support is important for high ac...
متن کاملCompetition of CO and H2 for Active Oxygen Species during the Preferential CO Oxidation (PROX) on Au/TiO2 Catalysts
Aiming at an improved mechanistic understanding of the preferential oxidation of CO on supported Au catalysts, we have investigated the competition between CO and H2 for stable, active oxygen (Oact) species on a Au/TiO2 catalyst during the simultaneous exposure to CO and H2 with various CO/H2 ratios at 80 ̋C and 400 ̋C by quantitative temporal analysis of products (TAP) reactor measurements. It...
متن کاملMetal Phosphate-Supported Pt Catalysts for CO Oxidation
Oxides (such as SiO₂, TiO₂, ZrO₂, Al₂O₃, Fe₂O₃, CeO₂) have often been used to prepare supported Pt catalysts for CO oxidation and other reactions, whereas metal phosphate-supported Pt catalysts for CO oxidation were rarely reported. Metal phosphates are a family of metal salts with high thermal stability and acid-base properties. Hydroxyapatite (Ca10(PO₄)₆(OH)₂, denoted as Ca-P-O here) also has...
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ژورنال
عنوان ژورنال: Brazilian Journal of Chemical Engineering
سال: 2020
ISSN: 0104-6632,1678-4383
DOI: 10.1007/s43153-020-00065-3